Fabrication and investigation of the properties of a water-based acrylic nanocomposite

Document Type : Research Paper

Authors

1 Master's Degree in Material Engineering - Nanomaterials from Shiraz University.

2 Professor of Engineering Department of Shiraz University

Abstract

 
     Nanocomposites are defined as systems that use engineered nano materials, like silica nanoparticles, which improve the final properties of the organic coatings. The main objective of this study is to fabricate a water based acrylic nanocomposite to achieve optimal weight percentage of silica nanoparticles as reinforcement. The organic coatings were prepared by a special formulation in which silica nano particles of 0.5, 0.75, 1.0, and 1.25 weight percent were incorporated into the organic coatings matrix. The adhesion, pencil hardness, microhardness (Vickers), wear, roughness measurement of the film surface, water resistance viscosity tests were performed to evaluate rheological, physical, mechanical and chemical properties of the nanocomposites. Moreover, scanning electron microscopy (SEM) and optical microscopy (OM) were employed to study the morphology and the time span for film's drying were measured. The results of SEM and OM showed that the silica nanoparticles were well dispersed up to 1.0 wt% loading and the adhesion properties, between the matrix and reinforcement particles, will be enhanced. Besides, the paint properties were optimized as 1 wt% of nanoparticles were loaded.

Keywords


References:
1-M. Baneshi, H. Gonome, A. Komiya, and S. Maruyama, “The effect of particles size distribution on aesthetic and thermal performances of polydisperse TiO 2 pigmented coatings: Comparison between numerical and experimental results, Journal of Quantitative Spectroscopy and Radiative Transfer”., vol. 113, no. 8, pp. 594–606, 2012.      
2-A. S. Khanna, “Nanotechnology in High Performance Paint Coatings Nanotechnology in Coating Industry Unique Properties of Nanoparticles Nano coating,” Polymer. Sc” vol. 21, no. 2, 2008.
3-         Z. Chen, T. Gang, K. Zhang, J. Zhang, X. Chen, Z. Sun, and B. Yang, “Ag nanoparticles-coated silica – PMMA core-shell microspheres and hollow PMMA microspheres with Ag nanoparticles in the interior surfaces,” Colloids and Surfaces A: Physicochemical and Engineering Aspects' vol. 272, pp. 151–156, 2006.           
4-         A. Zhu, Z. Shi, A. Cai, F. Zhao, and T. Liao, “ARTICLE IN PRESS POLYMER Synthesis of core – shell PMMA – SiO 2 nanoparticles with suspension – dispersion – polymerization in an aqueous system and its effect on mechanical properties of PVC composites,” Colloid Polymer”. Sci vol. 27, pp. 540–547, 2008.
5-         Zou, HuaWu,  Shishan Shen, Jian “Chemical         Reviews “. vol 109 “pp. 3893-3957,2008.
 
6-         A. Dashtizadeh, M. Abdouss, H. Mahdavi, and M. Khorassani, “Acrylic coatings exhibiting improved hardness, solvent resistance and glossiness by using silica nano-composites,” Appl. Surf. Sci., vol. 257, no. 6, pp. 2118–2125, 2011.
7-         M. B. Rezvani, M. Atai, F. Hamze, and R. Hajrezai, “The effect of silica nanoparticles on the mechanical properties of fiber-reinforced composite resins,” J. Dent. Res. Dent. Clin. Dent. Prospects, vol. 10, no. 2, pp. 112–117, 2016.          
8-         Z. Wang, E. Han, F. Liu, and W. Ke, “Fire and Corrosion Resistances of Intumescent Nano-coating Containing Nano-SiO 2 in Salt Spray Condition,” Journal of Materials Science and Technology vol. 26, no. 1, pp. 75–81, 2010.
9-         S. L. Pagliolico, E. D. Ozzello, G. Sassi, and R. Bongiovanni, “Characterization of a hybrid nano-silica waterborne polyurethane coating for clay bricks,” J. Coatings Technol. Res., vol. 13, no. 2, pp. 267–276, 2016.           
10-       V. D. Chari, D. V. S. G. K. Sharma, P. S. R. Prasad, and S. R. Murthy, “Dependence of thermal conductivity in micro to nano silica,” Bulletin of Materials … vol. 36, no. 4, pp. 517–520, 2013. 
11-       T. Mizutani, K. Arai, M. Miyamoto, and Y. Kimura, “Application of silica-containing nano-composite emulsion to wall paint: A new environmentally safe paint of high performance,” Prog. Org. Coatings, vol. 55, no. 3, pp. 276–283, 2006.      
12-       Y. Guo, M. Wang, H. Zhang, G. Liu, L. Zhang, and X. Qu, “The Surface Modification of Nanosilica , Preparation of Nanosilica / Acrylic Core-Shell Composite Latex , and Its Application in Toughening PVC Matrix, Polymers and Polymer Composites” 2007.  
13-       B. J. Inkson, “Nanoscale Tribology , Energy Dissipation and Failure Mechanisms of Nano- and Micro-silica Particle-filled Polymer Composites, Tribology Letters” pp. 11–19, 2009.     
14-       S. Sprenger, “The effect of rubber micro-particles and silica nano-particles on the tensile fatigue behaviour of a glass-fibre epoxy composite, Journal of Materials Science” pp. 342–345, 2009.
15-       V. Dey, R. Kachala, A. Bonakdar, and B. Mobasher, “Mechanical properties of micro and sub-micron wollastonite fibers in cementitious composites,” Constr. Build. Mater., vol. 82, pp. 351–359, 2015.         
16-       A. Yunita, S. Marie, K. Fog, and A. Eliasson, “Journal of Petroleum Science and Engineering Towards the understanding of microbial metabolism in relation to microbial enhanced oil recovery,” J. Pet. Sci. Eng., no. October, pp. 0–1, 2016.   
17-       P. Kompoziti and O. J. A. Ani, “NANOSILICA-REINFORCED POLYMER COMPOSITES,” Materiali in Tehnologije vol. 47, pp. 285–293, 2013.
18-       H. Jaganathan and B. Godin, “Biocompatibility assessment of Si-based nano- and micro-particles ,” Adv. Drug Deliv. Rev., vol. 64, no. 15, pp. 1800–1819, 2012.         
19-       S. Zhou and G. Gu, “Study on the morphology and tribological properties of acrylic based polyurethane / fumed,” Physics vol. 9, pp. 1593–1600, 2004.
20-       M. Chen, S. Zhou, B. You, and L. Wu, “A Novel Preparation Method of Raspberry-like PMMA / SiO 2 Hybrid Microspheres, Macromolecules” macromolecoles" pp. 6411–6417, 2005.
21-       P. Cevik and A. Z. Yildirim-bicer, “The Effect of Silica and Prepolymer Nanoparticles on the Mechanical Properties of Denture Base Acrylic Resin,”prosthodontics" vol. 0, pp. 1–8, 2016.
22-       L. J. Lee, C. Zeng, X. Cao, X. Han, J. Shen, and G. Xu, “SCIENCE AND Polymer nanocomposite foams,”composites since and technology" vol. 65, pp. 2344–2363, 2005.   
23-       J. Kozakiewicz, I. Ofat, I. Legocka, and J. Trzaskowska, “Progress in Organic Coatings Silicone-acrylic hybrid aqueous dispersions of core – shell particle structure and corresponding silicone-acrylic nanopowders designed for modification of powder coatings and plastics . Part I – Effect of silicone resin composition on properties of dispersions and corresponding nanopowders,” Prog. Org. Coatings, vol. 77, no. 3, pp. 568–578, 2014.  

24-N. Zheng, K. Liu, X. Li, and Z. Zhang, “Preparation of super-hydrophobic nano-silica aqueous dispersion and study of its application for water resistance reduction at low-permeability reservoir,” vol. 7, pp. 526–528, 2012.  
25- Garcı´a, M.; de Rooij, M.; Winnubst, L.; van Zyl, W. E.; Verweij, H. J. Appl. Polymer. Sci.vol 108, pp. 3358-3365, 2004.