Optimizing synthesis parameters of silver nanowires by polyol method

Document Type : Research Paper

Authors

• Sayed Ahmad Hashempour Cheshmegol
• Ali Mashreghi

Department of Materials Science and Engineering, Shiraz University of Technology, Shiraz, Iran

10.30495/jnm.2022.29577.1948

Abstract

Introduction: Silver nanowires are 1D nanostructures, with diameter of 10 – 200 nm and length of 5-100 μm.  Recently, polyol method has been known as a successful method for synthesis of silver nanowires. In the present work, silver nanowires were synthesized using Polyol method. A precise parametric study was performed to determine the effect of temperature, the injection rate of silver nitrate solution and PVP solution, stirring rate of solution and amount of copper chloride on the final morphology of synthesized silver nanowires.
Methods: X-ray diffraction method was used to determine the crystal structure and phase purity of synthesized silver nanowire. The morphology and size of silver nanowires were obtained by Field-Emission Scanning Electron Microscope. Electrical sheet resistance and visible light transparency of synthesized silver nanowires were measured by four-point probe test and UV-V spectrophotometer, respectively.
Findings: According to the obtained results, the temperature of 158 ° C, the injection rate of 0.55 cc/min, the stirring rate of 300 rpm and the copper chloride solution of 0.08 cc were determined as the optimal conditions for synthesis of silver nanowire. The optimized Ag nanowire coating showed 60% light transmittance and sheet resistance of 28 Ω/sq.

Keywords

• Silver nanowires
• Chemical synthesis
• Polyol
• Transparency
• Sheet resistance

20.1001.1.22285946.1400.12.45.2.1

---

References

[1] S. Kaabipour, S. Hemmati, “A review on the green and sustainable synthesis of silver nanoparticles and one-dimensional silver nanostructures” Beilstein Journal of Nanotechnology, vol. 12, pp. 102-136, 2021.

[2] J. Jeevanandam, S. Krishnan,Y.S. Hii, et al. “Synthesis approach-dependent antiviral properties of silver nanoparticles and nanocomposites”  J. Nanostruct. Chem.  2022,

 [3]  سعید جعفری راد، لاله خدایی، جلال محمدی ، رزاق محمودی، آیدا پارسا آذر، تولید زیستی نانوپودر نقره و ارزیابی کاربردهای آن در تولید فراورده های بهداشتی، مجله مواد نوین/ جلد 8/شماره 1/پاییز 1396، صفحه 69-79.

[4] مریم ابارشی، ایمان عبدی، بررسی خاصیت ضد باکتریایی نانوذرات نقره و نانوکامپوزیت های پلی اتیلن- نقره، مجله مواد نوین/ جلد ٦/شماره ٢ /زمستان ١٣٩٤، صفحه 159-168.

[5] فردین قاسمی، سعیده داداشیان، فاطمه باورسی ها، سنتز نانوکامپوزیت‌های Fe3O4/SiO2/TiO2-Ag با ساختار هسته- پوسته و بررسی خواص مغناطیسی آن‌ها، مجله مواد نوین/ جلد 8/شماره 3 /زمستان ١٣٩7، صفحه 51-61.

[6] P. Zhang et al., "Silver nanowires: Synthesis technologies, growth mechanism and multifunctional applications," Materials Science and Engineering: B, vol. 223, pp. 1-23, 2017.

[7] S. Hemmati, M.T. Harris, D.P. Barkey, Polyol Silver Nanowire Synthesis and the Outlook for a Green Process, Journal of Nanomaterials, vol. 2020,

https://doi.org/10.1155/2020/9341983

[8] L. Cao, Q. Huang, J. Cui, H. Lin ,W. Li, Z. Lin, P. Zhang, Rapid and Facile Synthesis of High-Performance Silver Nanowires by a Halide-Mediated, Modified Polyol Method for Transparent Conductive Films, Nanomaterials, vol. 10, pp. 1139, 2020.

[9] Y. Sun, B. Gates, B. Mayers, and Y. Xia, "Crystalline silver nanowires by soft solution processing," Nano letters, vol. 2, no. 2, pp. 165-168, 2002.

[10] Y. Sun and Y. Xia, "Large‐Scale Synthesis of Uniform Silver Nanowires Through a Soft, Self‐Seeding, Polyol Process," Advanced Materials, vol. 14, no. 11, pp. 833-837, 2002.

[11] K. E. Korte, S. E. Skrabalak, and Y. Xia, "Rapid synthesis of silver nanowires through a CuCl-or CuCl2-mediated polyol process," Journal of Materials Chemistry, vol. 18, no. 4, pp. 437-441, 2008.

[12] L. Yang, T. Zhang, H. Zhou, S. C. Price, B. J. Wiley, and W. You, "Solution-processed flexible polymer solar cells with silver nanowire electrodes," ACS applied materials & interfaces, vol. 3, no. 10, pp. 4075-4084, 2011.

[13] J.-J. Zhu, C.-X. Kan, J.-G. Wan, M. Han, and G.-H. Wang, "High-yield synthesis of uniform Ag nanowires with high aspect ratios by introducing the long-chain PVP in an improved polyol process," Journal of Nanomaterials, vol. 2011, p. 40, 2011.

[14] S. Hemmati and D. P. Barkey, "Parametric Study, Sensitivity Analysis, and Optimization of Polyol Synthesis of Silver Nanowires," ECS Journal of Solid State Science and Technology, vol. 6, no. 4, pp. P132-P137, 2017.

[15] S. Coskun, B. Aksoy, and H. E. Unalan, "Polyol synthesis of silver nanowires: an extensive parametric study," Crystal Growth & Design, vol. 11, no. 11, pp. 4963-4969, 2011.

[16] B. Liu et al., "Stable and Controllable Synthesis of Silver Nanowires for Transparent Conducting Film," Nanoscale Research Letters, vol. 12, no. 1, p. 212, 2017.

[17] G. Haacke, "New figure of merit for transparent conductors," Journal of Applied Physics, vol. 47, no. 9, pp. 4086-4089, 1976.

[18] A. Moholkar, S. Pawar, K. Rajpure, P. Patil, and C. Bhosale, "Properties of highly oriented spray-deposited fluorine-doped tin oxide thin films on glass substrates of different thickness," Journal of Physics and Chemistry of Solids, vol. 68, no. 10, pp. 1981-1988, 2007.