Synthesis and characterization of bio-nanocomposite of FeOOH-AC and its application in the removal of methyl orange anionic dye

Document Type : Research Paper

Authors

1 Assistant Professor-Chemical Engineering Department- Yasouj University- Yasouj, Iran

2 Assistant Professor-Materials Engineering Department-Yasouj University, Yasouj, Iran

Abstract

Abstract
Introduction: Nowadays, due to the reduction of fresh water resources and the increase in demand in the world, the removal of various pollutants, such as dyes, from industrial wastewaters to reuse them has received much attention. Methods: In this research, activated carbon (AC) was synthesized by the chemical activation of apricot kernel shell, and then, this adsorbent was modified by iron-containing functional groups (FeOOH-AC) and used as an adsorbent in the removal of methyl orange from the aqueous solution. The properties of these adsorbents were characterized using BET, SEM, XRD, and FT-IR analyses. Findings: The matching of the equilibrium data with the Langmuir model showed that the adsorption process is single-layer and the maximum adsorption capacity of AC and FeOOH–AC absorbents equal 174.6 mg/g and 249 mg/g, respectively. The increase in adsorption capacity after modification is due to the positive adsorption sites of iron (Fe-O-H2+) on the surface of the modified adsorbent, which adsorb the methyl orange by electrostatic mechanism. Also, the physical adsorption due to the porous structure of the adsorbent and π-π interaction are the effective mechanisms in the adsorption of methyl orange on the FeOOH-AC adsorbent. The analysis of kinetic data with different models showed that the pseudo-second-order kinetic model is consistent with the experimental result. The spontaneity and exothermic nature of the adsorption process were determined by determining the thermodynamic parameters. Conclusion: The successive cycles of adsorption and desorption indicate the ability to regenerate and reuse the synthesized adsorbent, which can be a suitable option for use on the industrial scale.

Keywords


[1] Shaikh, W.A., Islam, R.U., Eakraborty, S., Stable silver nanoparticle doped mesoporous biochar-based nanocomposite for efficient removal of toxic dyes, J. Environ. Chem. Eng., 9, 104982, 2021.

[2] Jemai, R., Djebbi, M.A., Boubakri, S., Rhaiem, H. B., Haj Amara, A. B. Effective removal of methyl orange dyes using an adsorbent prepared from porous starch aerogel and organoclay, Colorants 2, 209-229, 2023.

[3] Majumdar, R., Shaikh, W.A., Chakraborty, S., Chowdhury, S.R., A review on microbial potential of toxic azo dyes bioremediation in aquatic system, S. Das, H.R. Dash. (Eds.), Microbial Biodegradation and Bioremediation, Elsevier, 241-261, 2022.

[4] Nikfar, S., Jaberidoost, M., Dyes, Colorants, J.L. Coz Encyclopedia of Toxicology, Elsevier, 252-261, 2014.

[5] Rafii, F., Hall, J.D., Cerniglia, C., Mutagenicity of azo dyes used in foods, drugs and cosmetics before and after reduction by Clostridium species from the human intestinal tract, Food Chem. Toxicol., 35, 897-901, 1997.

[6] Shaikh, W.A., Chakraborty, S., Islam, R.U., UV-assisted photo-catalytic degradation of anionic dye (Congo red) using biosynthesized silver nanoparticles: a green catalysis, Desalin. Water Treat., 130, 232-242, 2018.

[7] Shaikh, W.A., Chakraborty, S., Islam, R.U., Photocatalytic degradation of rhodamine B under UV irradiation using Shorea robusta leaf extract-mediated bio-synthesized silver nanoparticles, Int. J. Environ. Sci. Tech., 17, 2059-2072, 2019.

[8] Li, W.Y., Chen, F., Wang, S., Binding of reactive brilliant red to human serum albumin: insights into the molecular toxicity of sulfonic azo dyes, Protein Pept. Lett., 17, 621-629, 2010.

[9] Liu, S., Li, B., Qi, P., Yu, W., Zhao, J., Liu, Y., Performance of freshly generated magnesium hydroxide (FGMH) for reactive dye removal, Colloid Interface Sci. Commun., 28, 34-40, 2019.

[10] Mahmoodi, N.M., Bashiri, M., Moeen, S.H., Synthesis of nickel–zinc ferrite magnetic nanoparticle and dye degradation using photocatalytic ozonation, Mater. Res. Bull., 47, 4403-4408, 2012.

[11] Soleimani, M., Kaghazchi, T., Adsorption of gold ions from industrial wastewater using activated carbon derived from hard shell of apricot stones–An agricultural waste, Bioresour. Technol., 99, 5374-5383, 2008.

[12] Mariana, M., Abdul Khalil, H.P.S., Mistar, E.M., Yahya, E.B., Alfatah, T., Danish, M., Amayreh, M., Recent advances in activated carbon modification techniques for enhanced heavy metal adsorption, J. Water Process. Eng., 43, 102221, 2021.

[13] Cooper, A. M.; Hristovskib, K. D.; Möller, T.; Westerhoff, P.; Sylvester, P., The effect of carbon type on arsenic and trichloroethylene removal capabilities of iron (hydr) oxide nanoparticle-impregnated granulated activated carbons, J. Hazard. Mater., 183, 381–388, 2010.

[14] Ranjithkumar, V., Sangeetha, S., Vairam, S. Synthesis of magnetic activated carbon/α-Fe2O3 nanocomposite and its application inthe removal of acid yellow 17 dye from water, Journal of Hazardous Materials, 273, 2014, 127-135.

[15] Joshi, S., Garg, V. K., Kataria, N., Kadirvelu, K., Applications of Fe3O4@AC nanoparticles for dye removal from simulated wastewater, Chemosphere, 236, 2019, 124280.

[16] Saad, M., Tahir, H., Synthesis of carbon loaded γ-Fe2O3 nanocomposite and their applicability for the selective removal of binary mixture of dyes by ultrasonic, Ultrasonics Sonochemistry, 36, 2017, 393-408.

[17] Mahmoud, M. E., Khalifa, M. A., El Wakeel, Y. M., Header, M. S., Abdel-Fattah, T. M., Engineered nano-magnetic iron oxide-urea-activated carbon nanolayer sorbent for potential removal of uranium (VI) from aqueous solution, Journal of Nuclear Materials, 487, 2017, 13.

[18] Ho, Y. S., Review of second-order models for adsorption systems, J. Hazard. Mater., 136, 681-689, 2006.

[19] Sharififard, H., Rezvanpanah, E., Rad, S.H., A novel natural chitosan/activated carbon/iron bio-nanocomposite: Sonochemical synthesis, characterization, and application for cadmium removal in batch and continuous adsorption process, Bioresour. Technol., 270, 562-56, 2018.

[20] Sharififard, H., Soleimani, M., Performance comparison of activated carbon and ferric oxide hydroxide–activated carbon nanocomposite as vanadium(V) ion adsorbents, RSC Adv., 5, 80650, 2015.

[21] Sahu, J., Acharya, J., Meikap, B., Optimization of production conditions for activated carbons from Tamarind wood by zinc chloride using response surface methodology, Bioresour. Technol., 101, 1974-1982, 2010.

[22] Sharififard, H., Soleimani, M., Ashtiani, F.Z., Evaluation of activated carbon and bio-polymer modified activated carbon performance for palladium and platinum removal, J. Taiwan Inst. Chem., 43, 696-703, 2012.

[23] ASTM Standard, Designation D2866-94, Standard test method for total ash content of activated carbon, 2000.

[24] Denga Ramutshatsha-Makhwedzha, Avhafunani Mavhungu, Mapula Lucey Moropeng, Richard Mbaya; Activated carbon derived from waste orange and lemon peels for the adsorption of methyl orange and methylene blue dyes from wastewater; Heliyon 8 (2022) e09930.

[25] Gayathiri, M., Pulingam, T., Lee, K.T., Sudesh, Kumar., Activated carbon from biomass waste precursors: Factors affecting production and adsorption mechanism, Chemosphere, 294, 133764, 2022.

[26] Ramya, V., Murugan, D., Lajapathirai, C., Meenatchisundaram, S., Arumugam, S., A composite adsorbent of superparamagnetic nanoparticles with sludge biomass derived activated carbon for the removal of chromium (VI), J. Clean. Prod., 366, 132853, 2022.

[27] Zhou, G.; Fang, F.; Chen, Z.; He,Y.; Sun, H.; Shi, H. Facile synthesis of paper mill sludge-derived heterogeneous catalyst for the Fenton-like degradation of methylene blue. Catal. Commun. 2015, 62, 71–74.

[28] Kennedy, L.J., Vijaya, J.J., Sekaran, G., Effect of two-stage process on the preparation and characterization of porous carbon composite from rice husk by phosphoric acid activation, Ind. Eng. Chem. Res., 43(8), 1832-1838, 2004.

[29] Alsultan, A., Mijan, A., Taufiq-Yap, Y.H., Preparation of activated carbon from walnut shell doped la and Ca catalyst for biodiesel production from waste cooking oil, Mater. Sci. Forum, 840, 343-348, 2016.

[30] Budinova, T., Ekinci, E., Yardim, F., Grimm, A., Björnbom, E., Minkova, V., Goranova, M., Characterization and application of activated carbon produced by H3PO4 and water vapor activation, Fuel Process. Technol., 87, 899-905, 2006.

[31] Luo, Y., Dong, L, Yichao, C., Xiaoying, S., Qin, C., Xiaofeng, L., The performance of phosphoric acid in the preparation of activated carbon-containing phosphorus species from rice husk residue, J. Mater. Sci., 54(6), 5008-5021, 2019.

[32] Konaganti, V.K., Kota, R., Patil, S., Madras, G., Adsorption of anionic dyes on chitosan grafted poly (alkyl methacrylate)s, Chem. Eng. J., 158, 393-401, 2010.

[33] Jawad, A.H., Abdulhameed, A.S., Mastuli, M.S., Mesoporous crosslinked chitosan-activated charcoal composite for the removal of thionine cationic dye: comprehensive adsorption and mechanism study, J. Polym. Environ., 28(3), 1095-1105, 2020.

[34] Zhang, J., Lin, S., Han, M., Su, Q., Xia, L., Hui, H., Adsorption properties of magnetic magnetite nanoparticle for coexistent Cr(VI) and Cu(II) in mixed Solution, Water 12, 446,2020.

[35] Sahoo T. R., Prelot B., Adsorption processes for the removal of contaminants from wastewater: the perspective role of nanomaterials and nanotechnology. In: Nanomaterials for the detection and removal of wastewater pollutants micro and nano technologies, Elsevier 2020, 161-222.

[36] Depci, T.; Comparison of activated carbon and iron impregnated activated carbon derived from Gölbas¸ lignite to remove cyanide from water, Chem. Eng. J., 181– 182, 467– 478, 2012.

[37] Payami F, Tavakkoli H, Synthesis, Characterization and investigation of removal process of methylene blue dye by perovskite-type oxides nanoparticles La0.9Sr0.1FeO3, Journal of New Materials, 10, 145-168, 2019 (In Persian).

[38] Balram Singh Yadav, Sudip Dasgupta, Effect of time, pH, and temperature on kinetics for adsorption of methyl orange dye into the modified nitrate intercalated MgAl LDH adsorbent, Inorganic Chemistry Communications, 137, 2022, 109203.

[39] Ridha Lafi, Amor Hafiane; Removal of methyl orange (MO) from aqueous solution using cationic surfactants modified coffee waste (MCWs), Journal of the Taiwan Institute of Chemical Engineers, 58, 2016, 424-433.

[40] Abdullahi Haruna Birniwa,Umar Ali, Bashir Muhammad Jahun, Baker Nasser Saleh Al-dhawi, Ahmad Hussaini Jagaba, Cobalt oxide doped polyaniline composites for methyl orange adsorption: Optimization through response surface methodology, Case Studies in Chemical and Environmental Engineering, 9, 2024, 100553.

[41] Omid Moradi, Afshin Pudineh, Sajjad Sedaghat; Synthesis and characterization Agar/GO/ZnO NPs nanocomposite for removal of methylene blue and methyl orange as azo dyes from food industrial effluents, Food and Chemical Toxicology, 169, 2022, 113412.

[42] Brahim Abbou, Imane Lebkiri, Hanae Ouaddari, Abdelhay El Amri, Fatima Ezzahra Achibat, Lamya Kadiri, Abdelkarim Ouass, Ahmed Lebkiri, El Housseine Rifi, Improved removal of methyl orange dye by adsorption using modified clay: Combined experimental study using surface response methodology, Inorganic Chemistry Communications, 155, 2023, 111127.

[43] Billah, R. E. K., Zaghloul, A., bahsis, L., Oladoja, N. A., Azoubi, Z., taoufyk, A., Majdoubi, H., Algethami, J. S., Soufiane, A., López-Maldonado, E. A., Wasilewska, M., Elboughdiri, N. Multifunctional biocomposites based on cross-linked Shrimp waste-derived chitosan modified Zn2+@Calcium apatite for the removal of methyl orange and antibacterial activity. Materials Today Sustainability 25, 2024, 100660.

[44] Rahmatpour, A., Alizadeh Hesarsorkh, A. H., Chitosan and silica nanoparticles-modified xanthan gum-derived bio-nanocomposite hydrogel film for efficient uptake of methyl orange acidic dye. Carbohydrate Polymers, 328, 2024, 121721.

[45] Chen, J., Yan, Z., Zhang, S., Yue, L., Zhihua, Xu., Fabrication of agro–waste lotus leaf–derived adsorbent for effective removal of organic pollutants from water, Chemical Engineering Science 283, 2024, 119426.

[46] Jiang, T., Liang, Y., He, Y., Wang, Q., Activated carbon/NiFe2O4 magnetic composite: A magnetic adsorbent for the adsorption of methyl orange, Journal of Environmental Chemical Engineering, 3, 2015, Pages 1740.