In Situ fabrication of (Cu-Cr)-Al2O3 nanocomposite

Abstract

   (Cu-Cr)-Al2O3 nanocomposite with different contents of Al2O3 has been successfully produced by using mechanochemical routs. This approach involves mechanical milling of Cu, Al, CuO and Cr2O3 in a high energy ball mill to produce (Cu-Cr)-Al2O3 composite. Different amount of initial Cu contents has been used to control the adiabatic temperature, Al2O3 particles size and Al2O3 content in the final products. The results of micro structure analysis with scanning electron microscopy (SEM) and X-ray diffraction (XRD) studies showed that in the early stage of ball milling particles agglomeration occurred and subsequently a solid solution of Cr in Cu, Cu (Cr), formed. In next step reaction between solute Al and CuO resulted in formation of fine Al2O3 particles and fracture of particles caused particles refinement.  The results of X-ray diffraction showed that Al2O3 particles were very fine

Keywords


  1. Fogagnolo, M. Ruiz-Navas, H. Robert and M. Torralba. 2003,The effects of mechanical alloying on the compressibility of aluminium matrix composite powder, Materials Science and Engineering A, Vol355, 50-55.
  2. D. Cullity. 1984, Element of X-Ray Diffraction, second edition, Department of Metallurgical Engineering and Materials Science University of Notre Dame.
  3. Suryanarayana. 2001, Mechanical alloying and milling, Progress in Materials Science, Vol46, 1-184.
  4. Das, P. P. Chatterjee, I. Manna and S. K. Pabi, 1999, A Measure of Enhanced Diffusion Kinetics in Mechanical Alloying of Cu-18 at. % Al by Planetary Ball Milling, Scripta Mate, Vol41, 861-866.

D.Y. Ying and D.L. Zhang , Processing of Cu–Al2O3 metal matrix nanocomposite materials by using high energy ball milling”. 2000, Materials Science and Engineering A, 152-156.

D.Y. Ying and  D.L. Zhang. 2003, Solid state reactions between CuO and Cu(Al) or Cu9Al4 in mechanically milled composite powders, Materials Science and Engineering A361, 321–330.

Gschneidner, Jr. and L. Eyring. Handbook on the Physics and Chemistry of Rare Earths. 1997, edited by K.A., Elsevier Science B. g All rights reserved, Vol. 24.

  1. S. Motta, P. K. Jena, E. A. Brocchi and I. G. Solrzano. 2001,“Characterization of Cu–Al2O3 nano-scale composites synthesized by in situ reduction”, Materials Science and Engineering C, Volume 15, Issues 1-2, 175-177.
  2. K. Jena, E. A. Brocchi and M. S. Motta. 2001, In-situ formation of Cu–Al2O3 nano-scale composites by chemical routes and studies on their microstructures, Materials Science and Engineering A313, 180–186.

S.J. Hwang and J. Lee. 2005, Mechanochemical synthesis of Cu–Al2O3 nanocomposites”, Materials Science and Engineering A, Vol405, 140–146.

  1. Takacs. 2005, Self-sustaining reactions induced by ball milling, Progress in Materials Science, Vol405, 140-146.
  2. J. Liu, I. Ohnuma, R. Kainuma and K. Ishida, 1998, Phase equilibrium in the Cu-rich portion of the Cu–Al binary system, Journal of Alloys and Compounds, Vol264, 201 –208.
  3. Shengqi, Q. Xiaoyan, M. Mingliang, Zhou Jingen, Z. Xiulin and W. Xiaotian, Solid-state reaction of Al/CuO couple by high-energy ball milling. 1998, Journal of Alloys and Compounds, Volume 268, 211-214.
  4. Ying and D.L. Zhang. 2000, Solid-state reactions between Cu and Al during mechanical alloying and heat treatment, Journal of Alloys and Compounds, Vol311, 275 –282.

Zhang DL and  Richmond JJ. J, Analysis of Compressing and Shearing Behavior of Powders in High-Speed Elliptical-Rotor-Type Powder Mixer (HEM). 1999, ‘Mater Sci,  Vol33. 34-701.