Synthesis and characterization of copper based spinel coating on alumina substrate for spark plug aero-engine application

Document Type : Research Paper

Authors

1 Chemistry Department,Payame Noor University (PNU), Tehran 19395-3697, Iran

2 Department of Chemistry and Materials Engineering, Shahrood University of technology

Abstract

Abstract

The present study aims to synthesis and characterization of spinel coating for spark plug aero-engine application. At first spinel coatings were synthesized by mechanical alloying. The different spinel coatings with spinel different composition and modulation were applied on alumina substrate. The phase content of the samples was characterized by X-ray diffraction (XRD) method. The microstructure and thickness of the coatings were analyzed by scanning electron microscopy. Nano-hardness and Young’s modulus of the coating were measured by nano-indentation method. The electrical resistance of the coating was studied at different temperatures. The electrical wear resistance of the coating was evaluated by spark method. The XRD method confirmed the synthesis of copper based spinels. The coatings had a thickness of 19-22 μm with proper density. The average nano-hardness of the coatings was 10 GPa. The wear rate after 140000 of spark was less than 1% of coating weight. It was also found that the optimum modulation of the multilayer coating is 4 successive layers composed of CuFe2O4+CuCr2O4, followed by two layer of CuCr2O4 and again CuFe2O4+CuCr2O4 layer. The ratio of the components in the composite layers were 50:50 wt.%

Keywords


  1. Hill, R.J.,Craig, J.R.,and Gibbs, G.V., Systematics of the Spinel Structure Type.Phys. Chem. Miner. 1979, 4,317-339.
  2. Sabato, A.G., Molin, S., Javed, H., Zanchi, E., Boccaccini, A.R., Smeacetto, F., In-situ Cu-doped MnCo-spinel coatings for solid oxide cell interconnects processed by electrophoretic deposition.Ceram. Int. 2019, 45, 19148-19157
  3. Meng, X., Yaping, Y., Youbin,X., Research on Modeling and Faults Diagnosis of Aero-engine Ignition System. Open Autom. Control. Syst. J., 2014, 6, 885-893.
  4. Antoshkiv, O., Poojitganont, Th., Jehring, L., Berkholz,C., Main aspects of kerosene and gaseous fuel ignition in aero-engine.The Aeronaut. J. 2017, 121, 1779 – 1794
  5. Jankowiak,A, Blanchart, P.,Electricalbehaviour of ceramic composite materials for aero-engine igniters.Aerosp.Sci.Technol. 2006, 10, 207–216.
  6. Stephen, S. C., straubEashey, W., surface gap igniter. US005187404A, 1993.
  7. Riddle, F.H., Ceramic spark-plug insulators. J. Am. Ceram. Soc. 1949, 32, 333-346.
  8. Yousefi, M., Ghatee, M., Rezakazemi, M., Ghaderi, S. H., The effects of adding nano-alumina filler on the properties of polymer-derived SiC coating. Int. J. Appl. Ceram. Technol.2021, 18, 2197-2206.
  9. blanchart,F. A. J. P., laigneauCollardey, D.,Method For preparing A Semi-Conductive Ceramic Material And ignition Plug Using This Ceramic Material. U.S. Patent : 200600030912006.
  10. Burland, G. N., Goreham, K., Taunt, R.,The development of the High Energy surface discharge spark igniter. Am. Soc. Mech. Eng. 1984, 3, 1-7.
  11. Bayón, R., Vicente, G.S., Maffiotte, C., Morales, Á., Preparation of selective absorbers based on CuMn spinels by dip-coating method. Renew. Energy 2008, 33, 348–353.
  12. Cui, H., Zayat, M., Levy ,D., Sol-gel synthesis of NanoscaledSpinelsUsing Propylene Oxide as a Gelation Agent.J. Sol-Gel Sci. Technol.2005, 35, 175–181.
  13. Auerkari, P., Mechanical and physical properties of engineering alumina ceramics. VTT Technical Research Centre of Finland1996.
  14. Coble, R.L., and Kingery, W.D.,Effect ofPorosity on Physical Properties of Sintered Alumina. J. Am. Ceram. Soc. 2006, 39, 377-385.
  15. Ghatee, M., Salari, F., Electrical and Mechanical Properties of 5YSZ Tubular Thin Film Prepared by Screen Printing Method. Int. J. of Appl. Ceram. Tech. 2016, 13, 373-381.
  16. Laokul, P., Amornkitbamrung, V., Seraphin, S., Maensiri, S., Characterization and magnetic properties of nanocrystallineCuFe 2O 4 ,NiFe 2O4 , ZnFe 2O4 powders prepared by the Aloe vera extract solution.Curr. Appl. Phys.2010, 11, 101–108.
  17. Doremusa, R. H.,Diffusion in alumina. J. Appl. Phys. 2006, 100, 101301-101307.
  18. Lesage,B., Huntz, A. M., Petot-ervas, G.,Transport phenomena in undoped and chromium or yttrium doped-alumina. Radiat. Eff. 1983, 75, 283–299.
  19. Anderson, R. L., Aviation Spark Plug Operational Factors. SAE Transact.1966, 74, 232-251.
  20. Liu,G., CuCr2O4 Spinel Ceramic Pigments Synthesized by Sol-Gel Self-Combustion Method for Solar Absorber Coatings.J. Mater. Eng. Perform.2016, 25, 2814-2823.